Hydrogen Basics

Brushing up basic chemistry concepts

Before start going into the basics of hydrogen, let’s remind ourselves of the difference between element, atom, molecule and compound. Element is a substance that we cannot break down further to any other substance. And that smallest amount of element is called an atom. But then what is an atom? An atom is a basic unit of an element that defines its structure. An atom consists of a nucleus and orbit/s. Protons and neutrons live in the nucleolus, and electrons move in orbits.

hydrogen basic structure
A simple form of hydrogen with an electron in the orbit and proton in the nucleus.

On the other hand, a molecule is made up of two or more atoms and chemically bonded such as H2, O2, H2O, C17H20N4NaO9P etc. A compound is a substance composed of two or more different types of chemically combined elements in a fixed proportion. Remember that all molecules are not compounds, but all compounds are molecules. H2O is both a molecule and a compound.

What is hydrogen?

Some Key Properties Of Normal Hydrogen
Atomic Hydrogen
Atomic Number1
Atomic Weight1.008
Electron Affinity0.7542 electron volts
Electronegativity (Pauling)2.1
Ionization Potential13.595 electron volts
Nuclear Magnetic Moment (Nuclear Magnetons)2.7927
Nuclear Quadrupole Moment0
Nuclear Spin1/2
Molecular Hydrogen
Boiling Point−252.77 degrees Celsius
Melting Point−259.20 degrees Celsius
Bond Distance0.7416 angstrom
Critical Density0.0310 gram per cubic centimetre
Critical Pressure13.0 atmospheres
Critical Temperature−240.0 degrees Celsius
Density of Liquid0.07099 (−252.78 degrees)
Density of Solid0.08671 gram per cubic centimetre
Dissociation Energy (25 Degrees C)104.19 kilocalories per mole
Heat of Combustion to Water (g)−57.796 kilocalories per mole
Heat of Fusion28 calories per mole
Heat of Vaporisation216 calories per mole
Ionization Potential15.427 electron volts
Source: H2 Bulletin, Encyclopedia Britannica, Literature Review, Royal Society of Chemistry

Hydrogen is denoted with a symbol ‘H’ is a colourless, odourless, tasteless and highly combustible gas. It is the lightest and simplest form of element in the universe. It is so simple that it is the only element in the periodic table which has no neutron. Atomic hydrogen is number 1 on the periodic table of elements.

The atom in atomic hydrogen has one proton in its nucleus with a positive electrical charge and one electron in a single orbit with a negative electrical charge. Hydrogen rarely exists in its simplest form as its unpaired electron try to get together with another electron. Hydrogen in its molecular form is more common. Molecular hydrogen (H2) is a form of hydrogen gas, and it comes into existence when two hydrogen atoms combine. Therefore, at its molecular form, hydrogen consists of two protons and two electrons and makes up the smallest molecule. It is 50,000 times smaller than the thickness of a hair. Being the smallest, it can enter anywhere. Hydrogen cannot be store in plastic made materials as it is too easy for it to pass through the plastic walls. Therefore, it requires special metal containers for storage.

Key milestones in the history of hydrogen

1671: Anglo-Irish Scientist Robert Boyle produced hydrogen gas for the first time while experimenting with iron and acids.

1766: British physicist Henry Cavendish first identified hydrogen as a distinct element. During his experiment, he evolved hydrogen gas by reacting zinc metal with hydrochloric acid.

1783: French physicist, Jacques Alexander Cesar Charles, launched the first hydrogen balloon flight.

1783: French chemist Antoine Lavoisier named the gas hydrogène which is derived from the Greek word “hydro” and “genes,” meaning “water” and “born of.”

1838: German-Swiss chemist Christian Friedrich Schönbein invented the fuel cell, which led to power generation out of hydrogen and oxygen.

1842: British Physicist Sir William Grove developed the first fuel cell which produced electrical energy by combining hydrogen and oxygen. He is called Father of the Fuel Cell.

1898: Scottish scientist Sir James Dewar turned hydrogen to a liquid form by cooling it down to -252.87°C.

1921: German physical chemist Karl Friedrich Bonhoeffer and Austrian chemist Paul Harteck works showed the two types of molecules: ortho-hydrogen and para-hydrogen.

Is hydrogen the most abundant element in the world?

No. In the universe (not on our planet earth), hydrogen is the most abundant element and accounts for 75% of the share, followed by helium which accounts for 24%. Together these two elements account for 99% of the universe. However, please do not confuse these figures with our planet earth.

The Most Abundant Elements in the Universe

The Most Abundant Elements in the Earth’s Atmosphere

Elemental Composition of Earth's Ocean Water

Elements in the Earth's Crust

Indeed hydrogen exists in abundance as a compound such as water, part of living bodies, carbon compounds, and atmosphere. However, it is not the most abundant element in the world. The chemical composition of our earth is slightly different from that of the universe.

The earth crust’s chemical composition consists of oxygen, the leading element with 46.10% of weight, followed by silicon, aluminium, iron, calcium, sodium, potassium, and magnesium. The crust is only the outer body of the earth which is between 5km to 10km. However, very little is known about the core and mantle, though the amount of hydrogen is considered negligible. The earth atmosphere is almost 99% composed of nitrogen and oxygen, so very little hydrogen can be found in the form of gas or vapour. The only part where we can find abundant hydrogen is water, though it still paired with oxygen as a compound.  Water covers 71% of the earth’s surface, whereas the oceans account for about 96.5% of all earth’s water. In ocean water, hydrogen accounts for around 10.8% of the total mass.

 

Most Abundant Elements in the Earth’s Crust
ElementAbundance % by weight
Oxygen46.10%
Silicon28.20%
Aluminium8.23%
Iron5.63%
Calcium4.15%
Sodium2.36%
Magnesium2.33%
Potassium2.09%
Titanium0.57%
Others0.34%
Source: H2 Bulletin, Jefferson Lab, Literature Review

Researchers are working on offshore electrolysis technology to produce hydrogen from seawater by using wind energy. Running the electrolysis process in a marine environment is complicated and faces numerous challenges. If such technology succeeds, it could be a significant breakthrough for the hydrogen industry. The hydrogen produced from water by using renewable energy is called green hydrogen. But the word green does not refer to the gas colour but classification as we now already know that hydrogen is colourless. Learn more about various types of hydrogen and how they are classified.


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