Hydrogen fuel cells produce clean electricity, generating only water as a byproduct. Developing efficient and inexpensive catalysts with improved performance in hydrogen production from water splitting is, therefore, imperative.
Now, researchers from Chung-Ang University make use of metal-organic frameworks and transition metal hydroxides to this end.
Among the several methods available for hydrogen generation, splitting water using electricity in the presence of a catalyst, or “electrocatalytic water splitting,” as it is called, is the cleanest. Unfortunately, the process requires expensive and rare noble metal catalysts, such as platinum, to maintain reasonable efficiency. This, in turn, has limited its large-scale industrial applications.
A relatively inexpensive option is transition metal-based catalysts, such as oxides, sulfides, hydroxides of cobalt, nickel, iron etc. However, there is a catch: the electrocatalytic water splitting consists of two half-reactions, namely the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER).
In OER, water molecules are oxidized to form oxygen and positive hydrogen ions at the anode (positively charged electrode). The hydrogen ions then move across the electrolyte to the cathode (the negatively charged electrode), where they are reduced to produce hydrogen (HER). It turns out that most transition metal-based catalysts reported so far can only catalyze either HER or OER. This makes for a complicated configuration and a higher overall cost.
Against this backdrop, researchers from Chung-Ang University in Korea developed, in a new study, a novel heterostructured catalyst consisting of hollow cobalt sulfide (CoSx) and nickel-iron (NiFe) layered double hydroxide (LDH) nanosheets that simultaneously boosts both the half-reactions.
Hollow HER catalysts are believed to be ideal for this job. It turns out that metal – organic frameworks (MOFs) are an efficient precursor for fabricating hollow structures. However, an MOF-based hollow catalyst with NiFe LDH has not be reported so far.
The catalyst consistently delivered a high current density of 1000 mA cm-2 in both half-reactions at low cell voltages, suggesting its feasibility for industrial-scale water-splitting applications. The researchers attributed this to the presence of ample active sites on the catalyst heterostructure, which enabled electrolyte penetration and gas release during the reactions. Additionally, an electrolyzer based on this catalyst demonstrated a high current density of 300 mA cm-2 at a low cell voltage and durability of 100 hours in overall water splitting.
Assistant Professor Seung-Keun Park, who headed the study, said, “The integration of an active HER catalyst, CoSx and an OER catalyst, NiFe LDH, guarantees a superior bifunctional catalytic activity.”